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that place is in the south of the city其中介词用in 为什么,在什么情况下用on,

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that place is in the south of the city其中介词用in 为什么,在什么情况下用on,at分别举例下
This is not an easy question to answer.Let's discuss some examples:
Guangzhou is in the south of China.--- Duangzhou is in China,but in the south of China.
India is on the south of China.--- India is not in China,but on the south of China.
To say "at the south of..." is not common.It appears in some phrases such as:
He arrived at the South of Human.
再问: India is on the south of China,可是老师说在外部的话是用TO,那to和on 到底该怎么用
再答: to 也可以, 有接临,接壤的意思。For example, Hunan is to the south of Hubei. That means, not only is Hunan on the south of Hubei, they also share a section of boundary. Usually, we do not say "Hunan is to the south of Henan". However, we could say Hunan is on the south of Henan.