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化工类英文科技文献译中文

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化工类英文科技文献译中文
There is a fair body of literature concerning the electroreduction of glucose.This has been reviewed by Fedoronko.He divided his review into the polarographic work and that done on solid electrodes.The polarographic studies form a coherent picture,in which the experimentally observed data,which take the form of a plateau,not diffusion controlled,are explained in terms of a rate-determining step of mutarotation from the cyclic (inactive) form of the sugar to the linear (electroactive) form.The process is known to be both acid and base catalyzed,and has been reviewed by Capon.It is generally assumed that no hydrogen evolution takes place in the polaro- graphic plateau region.
关于葡萄糖的电还原已有大量文献.对此,Fedoronko曾做过综述.他在综述中将这些工作分为极谱法和固态电极法两类.其中极谱法的工作已经给出了一个连贯的图像,这个图像把不受扩散控制的平台形实验数据解释为糖分子从环状结构(非活性状态)转化为线性结构(电活性状态)这一变旋反应的速率决定步骤.这个过程已知既可为酸催化又可为碱催化,Capon对此有过综述.通常认为在电极图形平台区域没有氢析出反应发生.