ptcl2的分子构型
来源:学生作业帮 编辑:作业帮 分类:英语作业 时间:2024/05/14 03:25:24
ptcl2的分子构型
In solid state,it exists in both polymeric,or "α",and hexameric,or "β" structures.The β form converts to the α form at 500 °C.In the β form,the Pt-Pt distances are 3.32-3.40 Å,indicative of some bonding between the pairs of metals.In both forms of PtCl2,each Pt center is four-coordinate,being surrounded by four chloride ligands.Complementarily,each Cl center is two-coordinate,being connected to two platinum atoms.
In solution,it likes to accommodate two more ligands to form square planar complex such as in Pt(NH3)2Cl2.
In solution,it likes to accommodate two more ligands to form square planar complex such as in Pt(NH3)2Cl2.